Rhodium
 

Rhodium

Rh redirects here. For other uses, see rh (disambiguation)
45 rutheniumrhodiumpalladium
Co

Rh

Ir
General
Name, Symbol, Number rhodium, Rh, 45
Chemical series transition metals
Group, Period, Block 9, 5, d
Appearance silvery white metallic
Standard atomic weight 102.90550(2)  g·mol−1
Electron configuration [Kr] 4d8 5s1
Electrons per shell 2, 8, 18, 16, 1
Physical properties
Phase solid
Density (near r.t.) 12.41  g·cm−3
Liquid density at m.p. 10.7  g·cm−3
Melting point 2237 K
(1964 °C, 3567 °F)
Boiling point 3968 K
(3695 °C, 6683 °F)
Heat of fusion 26.59  kJ·mol−1
Heat of vaporization 494  kJ·mol−1
Heat capacity (25 °C) 24.98  J·mol−1·K−1
Vapor pressure
P(Pa) 1 10 100 1 k 10 k 100 k
at T(K) 2288 2496 2749 3063 3405 3997
Atomic properties
Crystal structure cubic face centered
Oxidation states 4, 3, 2, 1[1]
(amphoteric oxide)
Electronegativity 2.28 (Pauling scale)
Ionization energies 1st: 719.7 kJ/mol
2nd: 1740 kJ/mol
3rd: 2997 kJ/mol
Atomic radius 135pm
Atomic radius (calc.) 173  pm
Covalent radius 135  pm
Miscellaneous
Magnetic ordering no data
Electrical resistivity (0 °C) 43.3 nΩ·m
Thermal conductivity (300 K) 150  W·m−1·K−1
Thermal expansion (25 °C) 8.2  µm·m−1·K−1
Speed of sound (thin rod) (20 °C) 4700 m/s
Young's modulus 380  GPa
Shear modulus 150  GPa
Bulk modulus 275  GPa
Poisson ratio 0.26
Mohs hardness 6.0
Vickers hardness 1246  MPa
Brinell hardness 1100  MPa
CAS registry number 7440-16-6
Selected isotopes
Main article: Isotopes of rhodium
iso NA half-life DM DE (MeV) DP
99Rh syn 16.1 d ε - 99Ru
γ 0.089, 0.353,
0.528
-
101mRh syn 4.34 d ε - 101Ru
IT 0.157 101Rh
γ 0.306, 0.545 -
101Rh syn 3.3 y ε - 101Ru
γ 0.127, 0.198,
0.325
-
102mRh syn 2.9 y ε - 102Ru
γ 0.475, 0.631,
0.697, 1.046
-
102Rh syn 207 d ε - 102Ru
β+ 0.826, 1.301 102Ru
β- 1.151 102Pd
γ 0.475, 0.628 -
103Rh 100% 103Rh is stable with 58 neutrons
105Rh syn 35.36 h β- 0.247, 0.260,
0.566
105Pd
γ 0.306, 0.318 -
References

Rhodium (pronounced /ˈroʊdiəm/) is a chemical element with the symbol Rh and atomic number 45. A rare silvery-white hard transition metal and a member of the platinum group, rhodium is found in platinum ores and is used in alloys with platinum and as a catalyst. It is usually the most expensive precious metal[2], though it is sometimes surpassed by rhenium, depending on the market.

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